Ion in IC(NH2)3]3A1F6 Single Crystals
نویسندگان
چکیده
X-band EPR spectra have been recorded at room temperature for V 0 2 + impurity in single crystals of t r is-Guanadiniumhexafluoroaluminate, [C(NH2)3]3A1F6 . 1 9 F super hyperfine structure has been observed on the 5 V hyperfine lines. V 0 2 + replaces Al 3 + to form an effective VOF5 complex. There are three possible V O bond orientations in the A1F6 octahedron but with differing occupancy factors. Bonding parameters have been evaluated.
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